The Skype application allows you to video-chat with people over the Internet, and you can also store a list of contacts that connect with the program. If you want to sync the contacts from your Skype program with your iPhone, you must enable the Contacts Manager add-in feature in Skype. With the Contacts Manager feature, you can export your selected contacts list to appear as a Comma Separated Values (CSV) file on your computer.
Open the Skype application on your computer and then click the "Tools" option from the top toolbar menu.
Move your mouse over the "Do More" option and then click the "Organize your extras" option. Click the "Miscellaneous" option.
Click the "Contacts Manager" option and download the add-in feature. Click the "My Extras" option after downloading the Contacts Manager.
Select all of the contacts that you want to sync with your iPhone and then click the "Export" button. Select the ".csv" option for the file format and then close out of the Skype application.
Click the "Start" button from your desktop and then click the "All Programs" option. Click the "Accessories" option and then click the "Address Book" option.
Click the "Shared Contacts" option and then click the "File" option from the top toolbar menu. Click the "Import" option and then click the "Other Address Book" option. Select the "Text File (Comma Separated Values)" option.
Minimize the address book and then open the iTunes application on your computer. Connect your iPhone to your computer using the USB connector.
Select the name of your iPhone in iTunes and then click the "Info" tab. Click the "sync" option and then select "Windows Address Book" from the drop-down menu. Click the "Apply" button.